In this tutorial...I will show you how to make PNG'S.
P = Portable
N = Network
G = Graphics
So first, pick the image you'd like to use.
I am using this one: (Click to Enlarge)

Now, go to the Toolbar on the Left side of your PSP9.
You will see a Little wand, change it to "Freehand Selection"
Now, there will be a toolbar uptop regarding to your Freehand Selection tool.
Just change the Selection type to "Point To Point"
Now all you do is go around your image with the selection tool. It's pretty simple.
And then when you are finished going around your image, right click on it, and press CTRL >> C >> V
Then your PNG should pop up and you can copy and paste it anywhere you like!
Heres mine: (Click to Enlarge)

haha...but it's not the greatest!!